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Fused Silica Blanks
Fused Silica Blanks
Fused Silica Blanks
Fused Silica Blanks

We supply various fused silica blanks such as tablet, rods, plate, block and other irregular shape which can be used to manufacture optical UV/IR lens, windows, rods, prisms and prototypes in the industries of Laser, optical fiber, photoelectric conversion elements, optical signal processing, optical storage, digital cameras, projectors, imaging scanners, monitors, laser printers, videophones, DVD, astronomical telescopes, vehicle, optical storage, electronic and consumer electronics, aviation, aerospace, ships, defense military and other optoelectronics.

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Materials include Nikon, Ohara, Corning, Heraeus and JGS1, JGS2, JGS3 high-precision synthetic quartz glass blanks used in far ultraviolet and infrared optical fields.

 

Features: High and low accuracy to meet the customer's demand for processing to save costs, provide special-shaped processing, small chipping, high transmittance, and high cost performance.

 

Size range:

Length:0-1000mm

Width: 0-700mm

Round:0-800mm

Specific dimensions: Guests specify the size.

If you can provide the required rough tolerances, parallelism, and roughness, you can get a faster quotation.

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You can send us your drawing or your findal products and we will match and quote for you.


General Properties
 
Synthetic Fused Silica
Synthetic fused silica is made from a silicon-rich chemical precursor by using a continuous flame hydrolysis process. Chemical gasification of silicon, oxidation of this gas to silicon dioxide, and thermal fusion of the resulting dust are involved in these processes, resulting in a transparent glass with a high purity and increased optical transmission in the deep ultraviolet. One common method involves adding silicon tetrachloride to a hydrogen-oxygen flame, but the use of this precursor brings some nature-unfriendly by-products such as hydrochloric acid. However, new processes (by using an alternative feedstock) have been developed to eliminate the by-products, which has also achieved a higher purity fused silica with further increased deep ultraviolet transmission.
 
Physical Properties
As a result of extremely low coefficient of thermal expansion, about 0.55 ppm/℃ (20-320℃), the fused quartz can undergo large, rapid temperature changes without cracking.
"UV grade" synthetic fused silica (trade names "HPFS", "Spectrosil" and "Suprasil"), can be transparent deeper into the ultraviolet due to its very low metallic impurity content. An optic with a thickness of 1 cm will have a transmittance of about 50% at a wavelength of 170 nm, which drops to only a few percent at 160 nm.
"IR grade" fused quartz (trade names "Infrasil", "Vitreosil IR"), being electrically fused, has more metallic impurities(limiting its UV transmittance wavelength to around 250 nm) and a much lower water content(achieving excellent infrared transmission up to 3.6 μm wavelength). Physical properties of all grades of transparent fused quartz/fused silica are near-identical.
To a large extent, manufacturing process of fused quartz and fused silica determines their water content and infrared transmission. Thanks to the combination of the hydrocarbons and oxygen fuelling the furnace forming hydroxyl [OH] within the material, flame fused material always has a higher water content. An IR grade material typically has an [OH] content of <10 parts per million.
 
 
Transmission rate of UV Fused Silica

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Thermal Properties
Quartz glass has a very low thermal coefficient of expansion (TCE) (5.0 × 10 –7/ ℃ on average), which is many times lower than that of other common materials. If 1 m3 blocks of borosilicate glass and quartz apparatus & wares were placed in a furnace and heated by 500 ℃, the volume of the borosilicate block would increase by more than 5 liters, while volume of quartz block would increase by less than one liter. Consequently, quartz glass is ideal quartz material to withstand very severe thermal shock.
Rapidly quench thin articles of quartz glass from over 1000 ℃ by plunging them into cold water without breakage is available. However, the thermal shock resistance depends on factors other than TCE such as surface condition and geometry. Varieties of used silica and fused quartz can be joined together with no added risk of thermally induced breakage due to their nearly identical TCE's.

Technical properties

Flame Fused Quartz

Fused Silica

Electrically Fused Quartz

Thermal data

Softening temperature (℃)

1660

1600

1710

Annealing temperature (℃)

1160

1100

1220

Strain temperature (℃)

1070

1000

1125

Max. working temperature continuous (℃)

1110

950

1160

Max. working temperature short-term (℃)

1250

1200

1300

Mean specific heat (J/kg · K)

0 ... 100 ℃

772

772

772

0 ... 500 ℃

964

964

964

0 ... 900 ℃

1052

1052

1052

Heat conductivity (W/m · K)

20 ℃

1.38

1.38

1.38

100 ℃

1.47

1.46

1.47

200 ℃

1.55

1.55

1.55

300 ℃

1.67

1.67

1.67

400 ℃

1.84

1.84

1.84

950 ℃

2.68

2.68

2.68

Mean expansion coefficient (K–1)

0 ... 100 ℃

5.1 × 10 –7

5.1 × 10 –7

5.1 × 10 –7

0 ... 200 ℃

5.8 × 10 –7

5.8 × 10 –7

5.8 × 10 –7

0 ... 300 ℃

5.9 × 10 –7

5.9 × 10 –7

5.9 × 10 –7

0 ... 600 ℃

5.4 × 10 –7

5.4 × 10 –7

5.4 × 10 –7

0 ... 900 ℃

4.8 × 10 –7

4.8 × 10 –7

4.8 × 10 –7

– 50 ... 0 ℃

2.7 × 10 –7

2.7 × 10 –7

2.7 × 10 –7

 
Mechanical Properties
Fused quartz material is very strong in compression, with design compressive strength is better than 1.1 x 10 9 Pa (160,000 psi). Because the inherent strength of any glass can be greatly reduced by surface flaws, tensile performance also can be greatly influenced, thus, the design tensile strength for fused quartz is more than 4.8 x 10 Pa (7,000 psi). In practice, a design stress of .68 x 10 Pa (1,000 psi) is recommended.

 

Mechanical Property

Reference Value

Density

2.203g/cm3

Compressive Strength

1100Mpa

Bending Strength

67Mpa

Tensile Strength

48.3Mpa

Poisson's Ratio

0.14-0.17

Elastic Modulus

71700Mpa

Shearing Modulus

31000Mpa

Moths Hardness

5.3-6.5(Moths Scale)

Deformation Point

1280℃

Specific Heat(20-350℃)

670J/kg.℃

Thermal Conductivity(20℃)

1.4W/m.℃

Refractive Index

1.4585

Coefficient of thermal expansion

5.5×10-7cm/cm.℃

Hot work temperature

1750-2050℃

The temperature for a short time

1300℃

The temperature for a long time

1100℃

Resistivity

7×107Ω.cm

Dielectric Strength

250-400Kv/cm

Dielectric Constant

3.7-3.9

Dielectric absorption coefficient

<4×104

Dielectric loss coefficient

<1×104

 
Chemistry Properties
Fused quartz, also named silica, is a non-crystalline form of silicon dioxide (SiO2). High purity is essential for fused quartz, which is mostly determined by the raw material, the manufacturing method and subsequent handling procedures. The most common impurities are metals (such as Al, Na and Fe), water (present as OH groups) and chlorine, which can affect the viscosity, optical absorption and electrical properties of the quartz glass. As a result, we have taken special precautions at all stages of manufacture to ensure high purity. In addition, we has different purification steps to improve the quality of the quartz sand.

NAME

UNIT X10-4%

Al

Fe

Ca

Mg

Yi

Cu

Mn

Ni

pb

Sn

Cr

B

K

Na

Li

OH

Fused Quartz

16

0.92

1.5

0.4

1.0

0.01

0.05

<0.3

<0.3

<0.3

<0.3

0.2

1.49

1.67

<0.3

400

Synthetic High-pure Fused Silica

0.37

0.31

0.27

0.04

0.03

0.03

0.01

<0.03

<0.03

<0.03

<0.03

0.02

0.5

0.5

<0.03

1200

Infrared Optical Quartz

35

1.45

2.68

1.32

1.06

0.22

0.07

<0.03

<0.03

<0.03

<0.03

0.3

2.2

3

<0.3

5

 
Electrical Properties
Fused quartz and fused silica have outstanding electrical strength that remains highly stable with temperature changes. Quartz resistivity (10 to 17th power) ohms/cc at 25 ℃ is in the order of (10 to 17th power) ohms/cc at 1000 ℃.
 
Electrical Resistance

Temperature ℃

Specific Resistance ℃M

Temperature ℃

Specific Resistance ℃M

20 100 200 300 400 500 600

10×1018 1×1018 10×1015 0.2×1012 5×109 0.3×109 60×106

700 800 900 1000 1100 1200 1300

10×106 4×106 2×106 1×106 0.7×106 0.5×106 0.4×106

 
Devitrification
The term “super-cooled liquid” refers to the fact that quartz glass should actually be a crystalline solid rather than a liquid, which can help us to understand why quartz glass devitrifies. The thermodynamically preferred state of quartz glass is crystalline, but the high viscosity prevents the structural rearrangement necessary to achieve it, i.e., compared to the relatively fast rate of cooling that quartz glass experiences, the molecules don't have the ability to arrange themselves quickly enough. However, this constraint can be removed resulting in the glass reverting to a crystalline state under certain conditions. For example, this usually happens at elevated temperature at the presence of a contaminant (like Alkalis like sodium or potassium) that drops the viscosity by breaking up the highly connected silicon-oxygen network as well as acting as a nucleating source.
This process is also exacerbated by the atmospheres which are high in water vapor or chlorine. The growth of the devitrified layer usually starts in the surface and progresses into the material at a rate that depends exponentially on temperature. The formed crystalline material is a high temperature form of silica, known as high cristobalite.
High cristobalite, with nearly the same density that glassy silica has, cannot be seen on the surface. However, upon cooling, high cristobalite changes from a cubic to a tetragonal crystal structure at about 275 ℃, which is accompanied by a large decrease in density resulting in some cracking and spalling. Refractive index differences, which result from the birefringent tetragonal crystal structure, cause the devitrified spots to turn white. 


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Key words:
SiO2,SiO2
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